“But what is it? You talk of it as if it were a bogey.”
“Why, they talk of it as if it were a bogey. And what could be a bogey to an Eekah? That is the most frightening aspect of it. So far, we know only that it involves the bombardment of an element they call plutonium-of which we have never heard and of which our own Eekahs have never heard either-by objects called neutrons, which our Eekahs say are subatomic particles without charge, which seems to us completely ridiculous.”
“And that is all?”
“All. Will you suspend judgment till we show you the sheets?”
Raph nodded reluctantly: “Very well.”
Raph’s leaden thoughts revolved in their worn groove as he stood there alone.
Eekahs and Primate Primeval. A living creature of erratic habits and a dead creature that must have aspired to heights. A sordid present of explosives and neutron bombardments and a glorious, mysterious past
No connection! No connection!
By June 1947 I had already been working on my Ph.D. research with near-total concentration (I was no longer working in the candy store; my younger brother, Stanley, had taken over) for nearly a year. I was in the homestretch and beginning to think forward to writing my Ph.D. dissertation. I rather dreaded that, since the obligatory style of dissertations is turgid in the extreme, and I had by now spent nine years trying to write well and was afraid I simply might not be able to write badly enough to qualify for my degree.
The experiments I was doing at the time required me, periodically, to dissolve a compound called catechol in water. The catechol existed in fine, feathery, fluffy needles that dissolved very readily in water. In fact, when I sprinkled catechol into the beaker of water, the individual needles dissolved as soon as they snuck the water surface. Idly, it occurred to me that if the catechol were any more soluble than it was, it would dissolve before it snuck the water surface.
Naturally, I thought at once that this notion might be the basis for an amusing story. It occurred to me, however, that instead of writing an actual story based on the idea, I might write up a fake research paper on the subject and get a little practice in turgid writing.
I did the job on June 8, 1947, even giving it the kind of long-winded title that research papers so often have-”The Endochronic Properties of Resublimated Thiotimoline”-and added tables, graphs, and fake references to non-existent journals.
I was not at all sure that “Thiotimoline” (no use trying to quote the entire name every time) was publishable. Astounding, however, ran serious articles on scientific subjects of particular interest to science fiction readers and I thought it just possible Campbell might be interested in a gag article that would be on the borders of science fiction.
I brought it in to him on the tenth, and he took it almost at once.
The Endochronic Properties of Resublimated Thiotimoline
The correlation of the structure of organic molecules with their various properties, physical and chemical, has in recent years afforded much insight into the mechanism of organic reactions, notably in the theories of resonance and mesomer-ism as developed in the last decade. The solubilities of organic compounds in various solvents has become of particular interest in this connection through the recent discovery of the endochronic nature of thiotimoline.
It has been long known that the solubility of organic compounds in polar solvents such as water is enhanced by the presence upon the hydrocarbon nucleus of hydrophilic - i.e., water-loving - groups, such as the hydroxy (-OH), amino (-NH2), or sulfonic acid (SO3H) groups. Where the physical characteristics of two given compounds - particularly the degree of subdivision of the material - are equal, then the time of solution - expressed in seconds per gram of material per milli-liter of solvent - decreases with the number of hydrophilic groups present. Catechol, for instance, with two hydroxy groups on the benzene nucleus, dissolves considerably more quickly than does phenol, with only one hydroxy group on the nucleus. Feinschreiber and Hravlek in their studies on the problem have contended that with increasing hydrophilism, the time of solution approaches zero. That this analysis is not entirely correct was shown when it was discovered that the compound thiotimoline will dissolve in water - in the proportions of 1 gm./ml. - in minus 1.12 seconds. That is, it will dissolve before the water is added.
Previous communications from these laboratories indicated thiotimoline to contain at least fourteen hydroxy groups, two amino groups and one sulfonic acid group. The presence of a nitro group (-NO2) in addition has not yet been confirmed, and no evidence as yet exists as to the nature of the hydrocarbon nucleus, though an at least partly aromatic structure seems certain of solution of thiotimoline quantitatively met with considerable difficulty because of the very negative nature of the value. The fact that the chemical dissolved prior to the addition of the water made the attempt natural to withdraw the water after solution and before addition. This, fortunately for the law of Conservation of Mass-Energy, never succeeded, since solution never took place unless the water was eventually added. The question is, of course, instantly raised as to how the thiotimoline can 'know' in advance whether the water will ultimately be added or not. Though this is not properly within our province as physical chemists, much recent material has been published within the last year upon the psychological and philosophical problems thereby posed.
Nevertheless, the chemical difficulties involved rest in the fact that the time of solution varies enormously with the exact mental state of the experimenter. A period of even slight hesitation in adding the water reduces the negative time of solution, not infrequently wiping it out below the limits of detection. To avoid this, a mechanical device has been constructed, the essential design of which has already been reported in a previous communication.6 This device, termed the endochronometer, consists of a cell 2 cubic centimeters in size into which a desired weight of thiotimoline is placed, making certain that a small hollow extension at the bottom of the solution cell - 1 millimeter in internal diameter - is filled. To the cell is attached an automatic pressure micro-pipette containing a specific volume of the solvent concerned. Five seconds after the circuit is closed, this solvent is automatically delivered into the cell containing the thiotimoline. During the time of action, a ray of light is focused upon the small cell-extension described above, and at the instant of solution, the transmission of this light will no longer be impeded by the presence of solid thiotimoline. Both the instant of solution - at which time the transmission of light is recorded by a photoelectric device - and the instant of solvent addition can be determined with an accuracy of better than 0.01 %. If the first value is subtracted from the second, the time of solution (T) can be determined.
The entire process is conducted in a thermostat maintained at 25.00° C. - to an accuracy of 0.01 ° C.
Thiotimoline Purity - The extreme sensitivity of this method highlights the deviations resulting from trifling impurities present in thiotimoline. (Since no method of laboratory synthesis of the substance has been devised, it may be practically obtained only through tedious isolation from its natural source, the bark of the shrub Rosacea Karlsbadensis rugo.) Great efforts were therefore made to purify the material through repeated recrystallizations from conductivity water - twice redistilled in an all-tin apparatus - and through final sublimations. A comparison of the solution times (T) at various stages of the purification process is shown in Table I.